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Layered Mercurocuprates Superconductivity Thermoelectricity .pdf


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Studies of High Temperature Superconductors,
A. Narlikar ed. v.44, Nova Science Publ., (New York, 2003) pp.1-80

The Structural, Superconducting, and
Transport Properties of the Mercurocuprates
and Other Layered Systems
A. L. Kuzemsky† , a and

I. G. Kuzemskayab

a

Joint Institute for Nuclear Research,
141980 DUBNA, Moscow Region, Russia
† e-m:kuzemsky@theor.jinr.ru; http://theor.jinr.ru/~kuzemsky
b

High Pressure Physics Institute, Russian Academy of Sciences,
142092 Troitsk, Moscow Region, Russia

Contents
1 Introduction

3

2 Layered Systems
2.1 Variety of Layered Materials . . . . . . . . . . . . . . . . . . .
2.2 Structural Sensitivity of Physical Properties . . . . . . . . . .

5
5
6

3 Layered Cuprates
3.1 Superconducting Copper Oxides . . . . . . . . . . . . . . . .
3.2 Crystal Chemistry Aspects . . . . . . . . . . . . . . . . . . .

8
8
9

4 Crystal Structure of Cuprates and Mercurocuprates
13
4.1 The Properties of the Hg-O Plane . . . . . . . . . . . . . . . . 18
1

5 Physical Properties of Layered Cuprates
20
5.1 Superconducting Plasma Oscillations in Josephson Array . . . 22
6 Layered Superconductor Models
24
6.1 Josephson Tunneling Model . . . . . . . . . . . . . . . . . . . 24
6.2 Models of Layered Cuprates . . . . . . . . . . . . . . . . . . . 27
6.3 Phenomenological Models of Cuprates . . . . . . . . . . . . . 27
7 Generalized Lawrence-Doniach Model
29
7.1 Identical Layers . . . . . . . . . . . . . . . . . . . . . . . . . . 30
8 Interlayer Effects in Layered Superconductors.
8.1 The Charge Redistribution . . . . . . . . . . . . . . . .
8.2 Role of Inequivalent CuO2 Layers . . . . . . . . . . . .
8.3 Tc and the Charge Carrier Density. . . . . . . . . . . .
8.4 Inequivalent Layer Models. . . . . . . . . . . . . . . . .
8.5 The n − m Layered Model. . . . . . . . . . . . . . . . .
8.6 Effect of Structure on the Density of Carriers . . . . .
8.7 Nonuniform Redistribution of Charge Among a-Layers
8.8 Critical Temperature and the MNY Model. . . . . . . .

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32
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35
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43

9 Transport Properties

46

10 TEP Measurements in the Cuprates

49

11 TEP in the Mercurocuprates

53

12 TEP and Models of Transport
12.1 Standard Transport Theory . .
12.2 Microscopic Models . . . . . . .
12.3 Semi-Phenomenological Models
12.4 Two-lifetime Model . . . . . . .

55
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57
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59

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13 Electron-Phonon Interaction Effects and TEP

63

14 Pressure Effects

64

15 Conclusions

67

16 Acknowledgements

69

2

Layered Cuprates and More on Magnesium Diboride: Studies of High...

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Contributors to Vol.44
Future volumes planned
Contents of earlier volumes
Preface
The Structural, Superconducting and Transport Properties of the Mercurocuprates and Other Layered Systems
A.L. Kuzemsky
I.G. Kuzemskaya
Introduction
Layered systems
Layered cuprates

v
vii
ix
xi

1
4
6

(3)
(2)
(5)

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