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# Spredox D 330 MSDS 2011 12 26 .pdf



Original filename: # Spredox D-330 - MSDS - 2011-12-26.pdf
Title: MSDS_AP-2500_EN
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Spredox® D-330 Polymeric Dispersant
1. Chemical product and company identification
1.1 Product name : Spredox® D-330
1.2 Synonym(s) : 1.3 General use : Coating Dispersant
1.4 Product description : Polymeric Dispersant
1.5 Manufacturer / Supplier :

2. Hazards identification
2.1 Classification of hazardous
Flammable liquids: Category 2
Acute Toxicity – Inhalation: Category 3
Skin Corrosion/Irritation: Category 3
Eye Damage/Irritation: Category 2B
Specific Target Organ Toxicity (Single Exposure) : Category 3
2.2 Label
Symbols:

Signal Word: Danger
Hazard Statements:
Highly flammable liquid and vapour.
Toxic if inhaled.
Causes mild skin irritation.
Causes eye irritation.
May cause drowsiness or dizziness.
Precautionary Statements:
Keep away from heat/sparks/open flames/hot surfaces. No smoking. Keep container tightly closed. Use
explosion-proof electrical/lighting/…/equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Wear protective gloves, eye/face protection. IF ON SKIN(or hair):
Take off immediately all contaminated clothing. Rinse skin with water/shower. Store in a
well-ventilated place. Keep cool. Store locked up. Avoid breathing dust/fume/gas/mist/vapours/spray.
Use only outdoor or in a well-ventilated area. IF INHALED: Remove person to fresh air and Keep
comfortable for breathing. Call a POISON CENTER/doctor/…/if you feel unwell. If skin irritation
occurs: Get medical advice/attention. Wash...thoroughly after handling. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If
eye irritation: Get medical advice/attention.

3. Composition / Information on ingredients
3.1 Chemical characterization : The product is a mixture
3.2 Hazardous components :
Chemical name
CAS number
Polyether Copolymer
Butyl Acetate, BAC
123-86-4

Wt %
50%
50%
Page 1 of 5

Spredox® D-330 Polymeric Dispersant
4. First aid measures
4.1 General :
Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to
affected area. Call an ambulance. Continue flushing during transport to hospital.
4.2 Inhalation :
Move injured person into fresh air and keep person calm under observation. Get medical attention if any
discomfort continues.
4.3 Eye contact :
Immediately flush with plenty of water for at least 20 minutes. Get medical attention if irritation
develops and persists.
4.4 Skin contact :
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention
promptly if symptoms occur after washing.
4.5 Ingestion :
Rinse mouth thoroughly with water and give large amounts of milk or water to people not unconscious.
Do not induce vomiting. If vomiting occurs, the head should be kept low so that stomach vomit doesn't
enter the lungs. Lay on the side. Get medical attention immediately.
4.6 Likely Acute or Delayed Symptoms/Effects:
Be aware that symptoms of chemical pneumonia (shortness of breath) may occur several hours after
exposure. Symptoms may be delayed.
4.7 Personal Protection for First-aid Responders:
First aid personnel should wear C grade protection equipment during rescue.
4.8 Note to physician :
Get medical attention if symptoms occur.

5. Fire fighting measures
5.1 Extinguishing Media :
Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog.
5.2 Unsuitable extinguishing media :
None.
5.3 Special Fire Fighting Procedures:
Use standard firefighting procedures and consider the hazards of other involved materials. Containers
close to fire should be removed or cooled with water.
5.4 Unusual Fire & Explosion Hazards:
During fire, gases hazardous to health may be formed. Solvent vapors may form explosive mixtures with
air.
5.5 Hazardous Combustion Products:
Carbon Dioxide, Carbon Monoxide
5.6 Protective Measures:
Selection of respiratory protection for fire fighting: follow the general fire precautions indicated in the
workplace. Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

6

Accidental release measures
6.1 Personal Precautions:
Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate the area.
Avoid
inhalation of vapors/spray and contact with skin and eyes. Wear suitable protective clothing. See
Section 8 of the MSDS for Personal Protective Equipment.
6.2 Spill Cleanup Methods:
Remove sources of ignition. Absorb spillage with non-combustible, absorbent material. Collect in
containers and seal securely.
For waste disposal, see section 13 of the MSDS.
6.3 Environmental Precautions:
Do not allow to enter drains, sewers or watercourses.
Page 2 of 5

Spredox® D-330 Polymeric Dispersant
7. Handling and storage
7.1 Handling :
Avoid contact with skin, eyes, or clothing. Wash thoroughly after handling. Use spark-proof tools and
explosion-proof equipment. Use only clean, dry, utensils in handling.
7.2 Storage :
Store at room temperature. Store in a cool dry place. Keep separated from incompatible substances. Store
in a tightly closed container. Grounding and bonding required.

8. Exposure controls and personal protection
8.1 Engineering controls :
Use explosion-proof ventilation equipment. Provide adequate ventilation. Observe Occupational
Exposure Limits and minimize the risk of inhalation of vapors. Provide easy access to water supply or an
emergency shower.
8.2 Exposure Limit Values:
Chemical name
Source
Type
Exposure Limits
Butyl Acetate
Taiwan OELS
TWA
150ppm
8.3 Personal protective equipment :
Respiratory Protection:
In case of inadequate ventilation and work of brief duration, use suitable respiratory equipment.
Eye Protection:
Wear approved safety goggles.
Hand Protection:
Wear protective gloves. Be aware that the liquid may penetrate the gloves. Frequent change is advisable.
Suitable gloves can be recommended by the glove supplier.
Skin Protection:
Wear appropriate chemical resistant clothing to prevent any possibility of skin contact.
8.4 Hygiene Measures:
Always observe good personal hygiene measures, such as washing after handling the material and
before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to
remove contaminants.

9. Physical and chemical properties
9.1 Molecular Weight:
9.2 Physical State:
9.3 Color :
9.4 Odor :
9.5 Odor threshold level :
9.6 pH :
9.7 Freezing point :
9.8 Boiling point :
9.9 Density
9.10 Specific gravity :
9.11 Vapor pressure :
9.12Vapor density (Air=1) :
9.13 Evaporation Rate:
9.14 % Volatile :
9.15 Solubility in water :
9.16 Solubility (Other):
9.17 Partition Coefficient (n-Octanol/water):
9.18 Flash point :
9.19 Autoignition Temperature:
9.20 Viscosity:
9.21 Explosion limit in air %

No data available.
Viscous liquid
Pale yellow
Fruity
No data available.
No data available.
No data available.
126.3oC (BAC)
0.95 g/cm3
0.95
15.0 mmHg at 25oC (BAC)
4 (BAC)
12 (Ether=1)(BAC)
No data available.
Partial solubility
No data available.
No data available.
22oC (Closed Cup) (BAC)
425oC(BAC)
No data available.
1.7-7.6% (BAC)
Page 3 of 5

Spredox® D-330 Polymeric Dispersant
9.22 Decomposition Temperature:

>250oC

10. Stability and reactivity
10.1 Chemical stability : Stable at normal temperature and pressure
10.2 Conditions to avoid :
Avoid heat, flames, sparks and other sources of ignition. Containers may rupture or explode if exposed
to heat.
10.3 Incompatibility with other materials: Combustible materials, acids, oxidizing materials, metal salts.
10.4 Hazardous decomposition products: Thermal decomposition products oxides of carbon, chlorine.
10.5 Hazardous polymerization: Will not polymerize.

11. Toxicological information
11.1 Acute effects
Product: No information available.
Acute inhalation effects :
Spray mist may irritate the respiratory system. In high concentrations, vapors are narcotic and may
cause headache, fatigue, dizziness and nausea. Exposed individuals may experience sore throat and
coughing.
Eye effects :
Causes eye irritation. May cause redness and pain.
Skin effects :
May be harmful in contact with skin. Causes skin irritation. May cause redness and pain. Defats the
skin.
Acute oral effects :
May be harmful if swallowed. May be fatal by entry into airways.
11.2 Sensitization: Not a skin sensitizer.
11.3 Carcinogenicity: Suspected of causing cancer.
11.4 Listed Carcinogens :--11.5 Mutagenesis: No data available.
11.6 Reproductive Toxicity: May damage fertility or the unborn child.
11.7 Other Effects:
Single exposure: May cause drowsiness or dizziness.
Repeated exposure: Causes damage to the following organs through prolonged or repeated exposure:
Liver.

12. Ecological information
12.1 Ecotoxicity: The product contains a substance which is harmful to aquatic organisms.
12.2 Mobility: The product contains organic solvents which will evaporate easily from all surfaces.
12.3 Persistence and Degradability: No data available.
12.4 Bioaccumulation Potential: No data available.
12.5 Other Adverse Effects:
The product contains a substance which has a photochemical ozone creation potential.

13. Disposal considerations
13.1 Product Disposal :
Comply with all federal, state and local regulations.
Do not dump this material into sewer, on the ground or into any body of water.
Dissolve or mix with a combustible solvent and burn in a chemical incinerator equipped with an
afterburner and scrubber.
13.2 Packaging Disposal : -

Page 4 of 5

Spredox® D-330 Polymeric Dispersant
14. Transport information
14.1 Land transport ADR / RID and GGVS /GGVE
ADR /RID
Shipping Name: Flammable liquid, n.o.s. (Butyl Acetate)
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: Flammable liquid, n.o.s. (Butyl Acetate)
IMDG-Code: 3
UN Number: 1993
Packing Group: III
IATA
Shipping Name: Flammable liquid, n.o.s. (Butyl Acetate)
ICAO/IATA Class: 3
UN Number: 1993
Packing Group: III
Packing Instruction(cargo aircraft): 366
Packing Instruction(passenger aircraft): 355
Packing Instruction(Limited quantity): Y344

15. Regulatory information
The product has been classified as dangerous according to the legislation in force “Rules on Hazard
Communication and Labels of Dangerous Materials and Toxic Materials (GHS)”

16. Other information
This MSDS contains revisions in the following section(s): Issue Date: 2011-June-16
Supersedes Date: 2011-December-26
Disclaimer: The information in this MSDS is based on currently available information. This MSDS does not
provide any guarantees as to the quality and safety of the product. The information is provided as general
information for safe handling of the product and the MSDS applies to normal use of the product. The
responsibility for use of the product in a special way which differs from the normal use lies with the user who
would take suitable safety measures.

Page 5 of 5


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