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Refrigeration Pedia
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REFRIGERATION
Heikal, Morgan R.
DOI: 10.1615/AtoZ.r.refrigeration
A refrigerator is a device which is designed to remove heat from a space that is at lower temperature
than its surroundings. The same device can be used to heat a volume that is at higher temperature than

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the surroundings. In this case the device is called a Heat Pump. The distinction between a refrigerator
and a heat pump is one of purpose rather than principle. Therefore, this section will concentrate on
refrigeration and only make the distinction between the two devices when necessary.
The Clausius statement of the Second Law of Thermodynamics asserts that it is impossible to construct a
device that, operating in a cycle, has no effect other than the transfer of heat from a cooler to a hotter
body. This means that energy will not flow from cold to hot regions without outside assistance. The
refrigerator and heat pump both satisfy the Clausius requirement of external action through the
application of mechanical power or equivalent natural transfers of heat.

Continuous refrigeration can be achieved by several processes. Effectively any heat engine cycle, when
reversed, becomes a refrigeration cycle. The vapor compression cycle is the most commonly used in
refrigeration and air condition applications. The vapor absorption cycle provides an alternative system,
particularly in applications where heat is economically available. Steam-jet systems are also being
successfully used in many cooling applications while air-cycle refrigeration is often used for aircraft
cooling. These cycles are described in detail in Look and Sauer (1988), and in the ASHRAE Handbook of
Fundamentals (1993). Refrigeration equipment is described in detail in the ASHRAE Handbook, HVAC
Systems and Equipment Volume (1992) and refrigerating systems practices are in the ASHRAE
Handbook, Refrigeration Volume (1990).
Reversed Heat Engine Cycles:
Mechanical refrigeration processes, of which the vapor compression cycle is an example, belong to the
general class of reversed heat engine cycles, Figure 1. This figure represents, schematically, the

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extraction of heat at rate from a cold body at temperature TC. The process requires the expenditure of
work W and the sum is discharged at a higher temperature TH.
Reversed heat engine cycle.
Figure 1. Reversed heat engine cycle.

The ideal cycle against which any practical reversed heat engine may be compared is the reversible or
Carnot Cycle for which, in accordance with the Second Law of Thermodynamics, the following
relationship applies:
One measure of the efficiency of such a process is given by:
Clearly the smaller the value of the ratio the more efficient is the process.
It is more usual to describe the efficiency of a reversed heat engine by the inverse of this ratio, known as
the Coefficient Of Performance (COP):
It will be observed that the COP may be greater than unity and that it becomes greater as the
temperature difference decreases. A real refrigerator or reversed heat engine will have a COP less than
that of the ideal Carnot Cycle engine as given by the above equation.
The reversed Carnot Cycle is represented on the Temperature-Entropy (T-S) diagram by a rectangle,
Figure 2, and is composed of four reversible processes;

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4-1 isothermal expansion, during which heat (the refrigeration load) flows from the cold space to the
working fluid.
1-2 adiabatic compression.
2-3 isothermal compression in which heat flows from refrigerant to the hot space.
3-4 adiabatic expansion.
Temperature-entropy diagram for ideal reversed Carnot Cycle.
Figure 2. Temperature-entropy diagram for ideal reversed Carnot Cycle.

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The Basic Vapor Compression Cycle and Components
Vapor compression refrigeration, as the name suggests, employs a compression process to raise the
pressure of a working fluid vapor (refrigerant) flowing from an evaporator at low pressure PL to a high
pressure PH as shown in Figure 3. The refrigerant then flows through a condenser at the higher pressure

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PH, through a throttling device, and back to the low pressure, PL in the evaporator. The pressures PL and
PH correspond to the refrigerant saturation temperatures, T1 and T5 respectively.
The T-S diagram for this real cycle, Figure 4, is somewhat different from the rectangular shape of the
Carnot Cycle.
Basic vapor compression refrigerator.
Figure 3. Basic vapor compression refrigerator.
T-S diagram for basic vapor compression cycle.
Figure 4. T-S diagram for basic vapor compression cycle.
The cycle processes can be described as follows:
7-1 Evaporation of the liquefied refrigerant at constant temperature T1 = T7.
1-2 Superheating of the vapor from temperature T1 to T2 at constant pressure PL.
2-3 Compression (not necessarily adiabatic) from temperature T2 and pressure PL to temperature T3
and pressure PH.
3-4 Cooling of the super-heated vapor to the saturation temperature T4.
4-5 Condensation of the vapor at temperature T4 = T5 and pressure PH.
5-6 Subcooling of the liquid from T5 to T6 at pressure PH.
6-7 Expansion from pressure PH to pressure PL at constant enthalpy.
A further difference between the real cycle and the ideal is that temperature T1 at which evaporation
takes place is lower than the temperature TL of the cold region so heat transfer can take place. Similarly
the temperature T4 of the heat rejection must be higher than the hot region temperature TH to bring
about heat transfer in the condenser.
It is usual for the vapor-compression cycle to be plotted on a pressure-enthalpy (p-h) diagram as shown
in Figure 5.
The cycle calculations are described in detail in many textbooks [e.g., Eastop and Mc Conkey (1993) and
Rogers and Mayhew (1992)].
Refrigerants
Refrigerants are the working fluids in refrigeration systems. They must have certain characteristics
which include good refrigeration performance, low flammability and toxicity, compatibility with

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compressor lubricating oils and metals, and good heat transfer properties. They are usually identified by
a number that relates to their molecular composition. The ASHRAE Handbook of Fundamentals (1993)
lists a large number of available refrigerants and gives their properties (see Refrigerants.)

In recent years, environmental concerns over the use of chlorofluorocarbons (CFCs) as the working fluids
in refrigeration and air-conditioning plants have led to the development of alternative fluids. The
majority of these fall into two categories, hydrofluorocarbons (HDCs) which contain no chlorine and
have zero ozone depletion potential and hydrochlorofluorocarbons (HCFCs), which do contain chlorine,
but the addition of hydrogen to the CFC structure allows virtually all the chlorine to be dispersed in the
lower atmosphere before it can reach the ozone layer. HCFCs therefore have much lower ozone
depletion potentials, ranging from 2 to 10% that of CFCs. Many nations have signed the Vienna
Convention which is a treaty intended to control the production of substances known to be depleting
the ozone layer. The Montreal Protocol to this treaty in 1987 outlines the means for achieving certain
limits in production of particular substances and the timetable for their phasing out. A great deal of
research is being carried out to determine the properties of new ozone friendly fluids and mixtures
[Sauer and Kuehn (1993)].
p-h representation of vapor compression cycles.
Figure 5. p-h representation of vapor compression cycles.

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Vapor-Absorption Cycles
Recently interest has been increasing in these cycles because of their potential use as part of energysaving plants and also because they use more environmentally friendly refrigerants than vaporcompression cycles. A basic vapor-absorption system is shown schematically in Figure 6. The condenser,
throttling valve and evaporator are essentially the same as in the vapor compression system (Figure 3).
The major difference is the replacement of the compressor with an absorber, a generator, and a solution
pump. A second throttling valve is also used to maintain the pressure difference between the absorber
(at the evaporator pressure) and the generator (at the condenser pressure).
The refrigerant on leaving the evaporator is absorbed in a low-temperature absorbing medium, some
heat, QA, being rejected in the process. The refrigerant-absorbent solution is then pumped to the higher
pressure and is heated in the generator, QG. Refrigerants vapor then separates from the solution due to
the high pressure and temperature in the generator. The vapor passes to the condenser and the weak
solution is throttled back to the absorber. A heat exchanger may be placed between the absorber and
the generator to increase the energy efficiency of the system. The work done in pumping the liquid
solution is much less than that required by the compressor in the equivalent vapor-compression cycle.
The main energy input to the system, QG, may be supplied in any convenient form such as a fuel burning
device, electrical heating, steam, solar energy or waste heat. Appropriate refrigerant/absorbent
combinations must be selected. One common combination uses ammonia as refrigerant and water as
absorbent. An alternative combination is water as refrigerant and lithium bromide as absorbent. There
are increasing research activities into finding suitable new combinations [Hodgett (1982)].
Basic absorption refrigerant system.
Figure 6. Basic absorption refrigerant system.
Simple gas-cycle refrigerant system.
Figure 7. Simple gas-cycle refrigerant system.
Gas-Cycle Refrigeration
Gas-cycle refrigeration, is essentially, a reversed Joule cycle (gas turbine cycle). As the name indicates,
the refrigerant in these systems is a gas. The system, as shown in Figure 7, is basically the same as that
of the vapor-compression cycle. The main difference is the replacement of the throttling valve by an
expander.
The cycle can be described as follows:
1-2

Adiabatic compression.

2-3

Constant pressure cooling.

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3-4

Adiabatic expansion.

4-1

Constant pressure heating (cooling effect).

As can be seen from Figure 7, the gas does not receive and reject heat at constant temperature, and,
therefore, the gas cycle is less efficient than the vapor cycle for given evaporator and condenser
temperatures. Gas-cycle systems are mostly used in air conditioning applications where the working
fluid-air can be ejected at T4. A common application is in the air conditioning of aircraft. Air, held from
the engine compressor, is cooled in a heat exchanger and then expanded through a turbine. The power
from the turbine is used to drive a fan which provides the cooling air for the heat exchanger. Air at T4 is
ejected into the cabin to provide the required cooling.

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