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An indirect dehalogenation reaction [Szatkowski and Dybala-Defratyka, Chemosphere 91 (2013) 258–264]’’ In their article, Szatkowski and Dybala-Defratyka (2013) conduct density functional theory calculations on 2-chlorophenol, 4-chlorophenol, 2,4,6-trichlorophenol and 4-chloro-2,6-dimethylphenol with the goal of describing ‘‘the mechanism of the dimerization reaction catalyzed by peroxidases and [to] predict whether it could be accompanied by chlorine isotopic fractionation when various chlorophenols are used as their substrates.’’ Peroxidases typically function at an optimum pH of 6 to 7, as is evident in the authors’ prior experimental work on halophenols (Szatkowski et al., 2011).